薪资第一和第二都可能有多名,所以需要group by
SELECT emp_no,salary FROM salaries s 
WHERE salary=
  (
    SELECT salary FROM salaries GROUP BY salary
    ORDER BY salary DESC LIMIT 1,1
  );

薪资第一和第二都可能有多名,所以需要group by
SELECT emp_no,salary FROM salaries s 
WHERE salary=
  (
    SELECT salary FROM salaries GROUP BY salary
    ORDER BY salary DESC LIMIT 1,1
  );